I’ve used the repair tool when this started and it did not really repair the file. I used the following combination of techniques to get the user working. In the Outlook data file cannot be accessed Folder Pane, you might see a folder named Recovered Personal Folders that contains your default Outlook folders or a Lost and Found folder.

Repair Outlook Data Files (.pst and .ost)

This is all most people will need, searching for older items will be slower but for daily use items it will still be quick. As you close them, lead to the folder and right-click on the OST file. Once you re-open Outlook, your OST file is automatically recreated or rebuilt. If your hard drive goes through any physical damage, it will damage the data across it too. A bad sector or corrupted hard drive can cause OST inaccessibility.

Outlook - OST file recurring corruption

Although the repair process might recreate some of the folders, they may be empty. The Outlook Stuck on Synchronizing Folders Lost and Found folder contains any folders and items recovered by the repair tool that Outlook can't place in their original structure. You can use the Inbox Repair tool (SCANPST.EXE) to diagnose and repair errors in your Outlook data file.

• Get your OST rebuilt properly with the help of the available techniques.
• There, lead into the "Data Files" tab and select your OST file.
• You could Right-click the Start button, and click Run, type Outlook.exe /safe, and click OK.
• Click the "Data Files" tab on the window and select your respective OST file.
• Confirmed user can log on to OWA (Office 365 webmail) without issue.
• Click the "Open File Location" button to lead to the folder automatically.

What are the major Reasons of OST Corruption and how to Fix it

When Outlook is running and is halted in such a way, it can damage the OST file. You might be working on something important across it when it happens. As you said Outlook E3 licenses should support at least 100GB of data & there’s no excuse why it can’t support OSTs above 50GB when they offer twice that space. In addition, you could open outlook in safe mode, maybe some add-ins affect the outlook. You could Right-click the Start button, and click Run, type Outlook.exe /safe, and click OK. Refer to this blog Solutions To Fix Error – "Errors Have Been Detected In The File Xxx.Ost" Solutions To Fix Error – "Errors Have Been Detected In The File Xxx.Ost" for the solution to this OST error.

Method 4: Use OST Repair Tool

Only way to restore Outlook 2016 (Windows) functionality was to create a new profile; this worked, and a new OST file was created. On the next screen, access the "Find File" option if you are unaware troubleshoot Outlook synchronizing folders error of the location. If you know the location, click on the "Add File" tab and browse it.